chatgpt润色经历（一）（1）输入要求+摘要

（一）:poe.com chatgpt润色（1）

输入1：（定位、要求等）

Please take on the role of a professional reviewer for the ACS Catalysis journal and give your opinion on my academic paper.

since your output length is limited, in order to save space，please use ellipses for the parts you don’t think need to be modified.

Note that in addition to giving the modified content, please also indicate which paragraphs and sentences have been modified in the revised version.

Please use the language More precise , concise, objective, coherent, consistent, academic

Make as few changes as possible

Embellish content according to the style of the ACS Catalysis journal

Because the paper is so long, I will only give you a small paragraph, and I will tell you where that small paragraph is in the paper each time, and you will only have to touch up that small paragraph individually each time.

Please think carefully and be sure to answer carefully, okay?

输出1：

Sure, I can certainly provide a professional review of your academic paper for the ACS Catalysis journal. Please provide the paragraph you would like me to focus on, and I will make the necessary modifications while adhering to the journal's standards for precision, concision, objectivity, coherence, consistency, and academic language.

输入2：（摘要）

The following is a summary: Inhibiting the formation of polycyclic aromatic hydrocarbons, the primary coke component in the hydrodeoxygenation process of bio-oil, remains an important challenge in bio-oil production from biomass. Herein, the elementary reactions routes and descriptors of coke formation during the hydrodeoxygenation (HDO) of bio-oil are unveiled firstly based on density functional theory calculations. (ⅰ) Two optimal paths leading to the coke formation of methylnaphthalene were sorted out by performing DFT calculation on the elementary reaction of toluene and butadiene on Pt-Pd (111). The rate-limiting elementary reaction was C-H (sp2) bond cleavage on the ring (S20→S21 and S24→S29). (ⅱ) Verified on the surface of six noble metals, we demonstrated that the elementary reaction energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) could be used as a descriptor of coke formation, which was in good agreement with the experimentally measured TG of coke. (ⅲ) The intrinsic properties of the catalyst, containing d-band center energy and the atomic spacing of the surface, could be used as descriptors for the reaction. Afterward, studying the effect of free radicals based on the descriptor, we found that the hydroxyl radical significantly reduced the rate-limiting energy barrier by 0.47 eV. Still, the hydrogen radical significantly increased the rate-limiting energy barrier by 0.60 eV. (ⅳ) The density of states analysis revealed strong electronic interaction between the hydrogen atom on the ring and free radicals, indicating the energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) still has certain applicability under the effect of free radicals. These results are helpful for the directional design and screening of anti-coking catalysts for HDO of bio-oil.

输出2：

The paragraph appears to be well-structured and provides a clear summary of the study's objectives and findings. However, there are opportunities to enhance the language and make it more precise, concise, and coherent. Based on the ACS Catalysis journal's standards, I have made the following modifications while indicating the modified sentences and paragraphs:

In the hydrodeoxygenation process of bio-oil, inhibiting the formation of polycyclic aromatic hydrocarbons (PAHs) - a primary coke component - remains a significant challenge in bio-oil production from biomass. In this study, we aimed to unveil the elementary reaction routes and descriptors of coke formation during the hydrodeoxygenation of bio-oil using density functional theory (DFT) calculations. Firstly, we sorted out two optimal paths leading to the coke formation of methylnaphthalene by performing DFT calculations on the elementary reaction of toluene and butadiene on Pt-Pd (111) (I). The rate-limiting elementary reaction was the cleavage of the C-H (sp2) bond on the ring (S20→S21 and S24→S29).

To verify the results, we demonstrated that the energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) could be used as a descriptor of coke formation, which was in good agreement with the experimentally measured thermogravimetric (TG) analysis of coke (II). Moreover, we found that the intrinsic properties of the catalyst, such as the d-band center energy and the atomic spacing of the surface, could be used as descriptors for the reaction. Using these descriptors, we studied the effect of free radicals and found that the hydroxyl radical significantly reduced the rate-limiting energy barrier by 0.47 eV, while the hydrogen radical significantly increased it by 0.60 eV (III).

Our density of states analysis revealed a strong electronic interaction between the hydrogen atom on the ring and free radicals, indicating that the energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) still has certain applicability under the effect of free radicals (IV). Overall, our findings provide insights into the elementary reaction routes and descriptors of coke formation during the hydrodeoxygenation of bio-oil, which can be used for the directional design and screening of anti-coking catalysts (V).

Modified sentences and paragraphs:

I. "Herein, the elementary reactions routes and descriptors of coke formation during the hydrodeoxygenation (HDO) of bio-oil are unveiled firstly based on density functional theory calculations." changed to "In this study, we aimed to unveil the elementary reaction routes and descriptors of coke formation during the hydrodeoxygenation of bio-oil using density functional theory (DFT) calculations. Firstly, we sorted out two optimal paths leading to the coke formation of methylnaphthalene by performing DFT calculations on the elementary reaction of toluene and butadiene on Pt-Pd (111) (I). The rate-limiting elementary reaction was the cleavage of the C-H (sp2) bond on the ring (S20→S21 and S24→S29)."

II. "Verified on the surface of six noble metals, we demonstrated that the elementary reaction energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) could be used as a descriptor of coke formation, which was in good agreement with the experimentally measured TG of coke." changed to "To verify the results, we demonstrated that the energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) could be used as a descriptor of coke formation, which was in good agreement with the experimentally measured thermogravimetric (TG) analysis of coke (II)."

III. "Afterward, studying the effect of free radicals based on the descriptor, we found that the hydroxyl radical significantly reduced the rate-limiting energy barrier by 0.47 eV. Still, the hydrogen radical significantly increased the rate-limiting energy barrier by 0.60 eV." changed to "Moreover, we found that the intrinsic properties of the catalyst, such as the d-band center energy and the atomic spacing of the surface, could be used as descriptors for the reaction. Using these descriptors, we studied the effect of free radicals and found that the hydroxyl radical significantly reduced the rate-limiting energy barrier by 0.47 eV, while the hydrogen radical significantly increased it by 0.60 eV (III)."

IV. "The density of states analysis revealed strong electronic interaction between the hydrogen atom on the ring and free radicals, indicating the energy barrier of C-H (sp2) bond cleavage on the ring (S20→S21) still has certain applicability under the effect of free radicals." changed to "Our density of states analysis revealed a strong electronic interaction between the hydrogen atom on